Both are backscattered twilight red, and they're two halves of one scene. The Belt of Venus is the pink anti-twilight arch in the sky opposite the sun, sitting above the blue band of Earth's own shadow. Alpenglow is that same light landing on a mountain face.
Side by side
Aspect
Alpenglow
Belt of Venus
Where
On a mountain
In the sky
Direction
Opposite the sun
Opposite the sun
Light source
Backscattered
Backscattered
Needs mountains
Yes
No
What each one means
Alpenglow
Alpenglow is the rosy or cherry-red glow on snow-covered mountains at sunrise or sunset. Strictly it means the indirect glow seen when the sun itself is already below the horizon; dictionaries also allow the looser sense of any reddish sunrise or sunset light on a summit.